Thermo-oxidatively stabilized polybenzimidazole-containing artic

Stock material or miscellaneous articles – Self-sustaining carbon mass or layer with impregnant or...

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264 291, 4234474, 427399, B32B 900

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active

052779815

ABSTRACT:
A process for enhancing the thermo-oxidation stability of a polybenzimidazole-containing article wherein the article contains from about 5 to about 100 weight percent of polybenzimidazole and from about 0 to about 95 weight percent of a thermoplastic polymer, by the steps of providing a phosphoric acid solution of about 2.0 to about 10.0 weight percent of acid; contacting the polybenzimidazole-containing article with the acid solution for sufficient time to produce an acid-treated article; drying the acid-treated article at a low temperature to remove excess acid; and heat treating the dried article at a temperature ranging from about 400.degree. to about 500.degree. C. in an inert atmosphere to form a phosphate barrier layer on the surface of the article, wherein the article retains at least about 50 percent of its weight after isothermal aging at about 600.degree. F. for a period of at least about 300 hours.

REFERENCES:
patent: 3449077 (1969-06-01), Stuetz
patent: 3886251 (1975-05-01), Sekiguchi et al.
patent: 3903248 (1975-09-01), Kalnin et al.

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