Earth boring – well treating – and oil field chemistry – Earth boring – Contains organic component
Reexamination Certificate
2001-08-15
2004-08-31
Tucker, Philip C. (Department: 1712)
Earth boring, well treating, and oil field chemistry
Earth boring
Contains organic component
C507S110000, C507S111000, C507S112000, C507S113000, C507S114000, C507S115000, C507S118000, C507S119000, C507S120000, C507S139000, C507S209000, C507S211000, C507S212000, C507S213000, C507S214000, C507S215000, C507S216000, C507S217000, C507S219000, C507S221000, C507S224000, C507S225000, C507S261000, C507S266000
Reexamination Certificate
active
06784140
ABSTRACT:
BACKGROUND OF INVENTION
1. Field of the Invention
The invention relates generally to the exploitation of hydrocarbon-containing formations. More specifically, the invention relates to the fields of fluid rheology, thickeners, viscosifiers, viscoelastic fluids, drilling fluids, well fracturing fluids, well treatment fluids and fluid control pills.
2. Background Art
When drilling or completing wells in earth formations, various fluids typically are used in the well for a variety of reasons. The fluid often is aqueous. For the purposes herein, such fluid will be referred to as “well fluid.” Common uses for well fluids include: lubrication and cooling of drill bit cutting surfaces while drilling generally or drilling-in (i.e., drilling in a targeted petroliferous formation), transportation of “cuttings” (pieces of formation dislodged by the cutting action of the teeth on a drill bit) to the surface, controlling formation pressure to prevent blowouts, maintaining well stability, suspending solids in the well, minimizing fluid loss into and stabilizing the formation through which the well is being drilled, fracturing the formation in the vicinity of the well, displacing the fluid within the well with another fluid, cleaning the well, testing the well, implacing a packer fluid, abandoning the well or preparing the well for abandonment, and otherwise treating the well or the formation. Brines (such as CaBr
2
) commonly are used as well fluids because of their wide density range and the fact that brines are typically substantially free of suspended solids. Additionally, brines typically do not damage certain types of downhole formations.
A variety of compounds typically are added to brine-based well fluids. For example, a brine-based well fluid also may include corrosion inhibitors, lubricants, pH control additives, surfactants, solvents, and/or weighting agents, among other additives. Some typical brine-based well fluid viscosifying additives include natural polymers and derivatives such as xanthan gum and hydroxyethyl cellulose (HEC).
Some synthetic polymer and oligomer additives such as poly(ethylene glycol)(PEG), poly(diallyl amine), poly(acrylamide), poly(aminomethylpropylsulfonate[AMPS]), poly(acrylonitrile), poly(vinyl acetate), poly(vinyl alcohol), poly(vinyl amine), poly(vinyl sulfonate), poly(styryl sulfonate), poly(acrylate), poly(methyl acrylate), poly(methacrylate), poly(methyl methacrylate), poly(vinylpyrrolidone), poly(vinyl lactam) and co-, ter-, and quater-polymers of the following co-monomers: ethylene, butadiene, isoprene, styrene, divinylbenzene, divinyl amine, 1,4-pentadiene-3-one (divinyl ketone), 1,6-heptadiene-4-one (diallyl ketone), diallyl amine, ethylene glycol, acrylamide, AMPS, acrylonitrile, vinyl acetate, vinyl alcohol, vinyl amine, vinyl sulfonate, styryl sulfonate, acrylate, methyl acrylate, methacrylate, methyl methacrylate, vinylpyrrolidone, and vinyl lactam are also often used.
The polymers and oligomers listed above have other uses in drilling applications as well. When drilling progresses to the level of penetrating a hydrocarbon bearing formation, special care may be required to maintain the stability of the wellbore. Examples of formations in which problems often arise are highly permeable and/or poorly consolidated formations. In these types of formations, a technique known as “under-reaming” may be employed.
In this process, the wellbore is drilled to penetrate the hydrocarbon bearing zone using conventional techniques. A casing generally is set in the wellbore to a point just above the hydrocarbon bearing zone. The hydrocarbon bearing zone then may be re-drilled, for example, using an expandable under-reamer that increases the diameter of the wellbore. Under-reaming usually is performed using special “clean” drilling fluids. Typical drilling fluids used in under-reaming are expensive, aqueous, dense brines that are viscosified with a gelling and/or cross-linked polymer to aid in the removal of formation cuttings. The high permeability of the target formation, however, may allow large quantities of the drilling fluid to be lost into the formation.
Once the drilling fluid is lost into the formation, it becomes difficult to remove. Calcium and zinc-bromide brines can form highly stable, acid insoluble compounds when reacted with the formation or substances contained therein. This reaction may reduce the permeability of the formation to any subsequent out-flow of the targeted hydrocarbons. The most effective way to prevent such damage to the formation is to limit fluid loss into the formation.
Thus, providing effective fluid loss control is highly desirable to prevent damaging the formation in, for example, completion, drilling, drill-in, displacement, hydraulic fracturing, work-over, packer fluid implacement or maintenance, well treating, or testing operations. Techniques that have been developed to control fluid loss include the use of fluid loss “pills.” Significant research has been directed to determining suitable materials for the fluid loss pills, as well as controlling and improving the properties of the fluid loss pills. Typically, fluid loss pills work by enhancing filter-cake buildup on the face of the formation to inhibit fluid flow into the formation from the wellbore.
Because of the high temperatures, high shear (caused by the pumping and placement), high pressures, and low pH to which well fluids are often exposed (i.e., “stress conditions”), the above described polymeric materials used to form fluid loss pills, and to viscosify the well fluids, tend to degrade rather quickly. It is believed that the water found in these aqueous systems may catalyze the degradation of the polymeric materials used in well fluid applications. Thus, reducing the amount of water in a given well fluid is important for improving the thermal durability of well fluids.
What is needed are well fluids that can withstand stress conditions for extended periods of time without significant degradation. In particular, what is needed is a simple, inexpensive way to increase the temperature range for viscosifying agents used in downhole applications. Preferably, such a thermal extender would be operable in the absence of water.
SUMMARY OF INVENTION
In one aspect, the present invention relates to a method of treating a well including injecting a thermally stable, substantially water-free well-treating fluid into the well, wherein the well-treating fluid comprises a polymer, a glycol compound, and a salt.
In another aspect, the present invention relates to a thermally stable, substantially water-free well fluid including a polymer, a diol compound, and a salt.
Other aspects and advantages of the invention will be apparent from the following description and the appended claims.
REFERENCES:
patent: 4498994 (1985-02-01), Heilweil
patent: 4567947 (1986-02-01), Mzik
patent: 5552377 (1996-09-01), Kindred
patent: 5785747 (1998-07-01), Vollmer
patent: 6451743 (2002-09-01), Fox
patent: 6489270 (2002-12-01), Vollmer
patent: WO 96/19545 (1996-06-01), None
patent: WO 97/10313 (1997-03-01), None
patent: WO 02/40612 (2002-05-01), None
International Search Report dated Jan. 24, 2003, 2 pages.
International Search Report dated Jan. 24, 2003, 2 pages.
Foxenberg William E.
Kippie David P.
M-I L.L.C.
Tucker Philip C.
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