Thermally stable, reactive organometallic compositions containin

Details Thermally stable, reactive organometallic compositions containin Thermally stable, reactive organometallic compositions containin

1990-02-02

1992-03-31

Miller, Edward A.

Compositions

Compositions containing a single chemical reactant or plural...

Inorganic reactant other than sulfur containing

C09K 300

Patent

active

051005751

ABSTRACT:
An organometallic composition containing copper(I) comprising:

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patent: 4952710 (1990-08-01), Babiak et al.
Lindstedt, E.; Nilsson, M., Acta Chemica Scandinavica B., 40, 466-469, (1986); 2-Thienyl as Auxiliary Group in Mixed Lithium Diorganocuprates.
Lindstedt, E.; Nilsson, M. Olsson, T., J. Organometallic Chem., 334, 255-61, (1987); From 2-Thienylcopper Couplings to Trimethylsilyl-promoted Organocopper Additions.
Malmberg, H.; Nilsson, M; Ullenius, C.; Tetrahedron Lett., 23(37), 3823-26, (1982), Stereoselectivity in the Transfer of the 2-(1-dimethylaminoethyl)phenyl Group, R*, From LiR.sub.2 Cu and Li(R*)(2-thienyl)Cu to Enones.
Andersson, S.; Jagner, S.; Nilsson, M.; Urso, F., J. Organometallic Chem., 301, 257-67, (1987); Steric Consequence of the Diastereoselective Addition of Chiral Lithium 2-(1-dimethylaminoethyl)phenyl Cuprates to Some Enones.
Lipshutz, B. H.; Koerner, M.; Parker, D. A., Tetrahedron Lett., 28(9), 945-48, (1987); 2-Thienyl(cyano)copper Lithium, A Lower Order, Stable "Cuprate in a Bottle" Precursor to Higher Order Reagents.
Martin, S. F.; Fishpaugh, R. R.; Power, J. M.; Giolando, D. M.; Jones, R. A.; Nunn, C. M.; Cowley, A. H., J. Am. Chem. Soc., 110, 7726-28, (1988); Structure and Reactivity of Novel Lithium Di-tert-butylphosphido(alkyl)cuprates.
Bertz, S. H.; Dabbagh, G.; J. Chem. Soc., Chem. Commun., 1030, (1982); Factors Governing the Thermal Stability of Organocopper Reagents. Two New Classes of Heterocuprates with Greatly Improved Thermal Stability.
Bertz, S. H.; Dabbagh, G; J. Org. Chem., 49, 1119, (1984); Dicyclohexylphosphide as an Auxiliary Ligand for Thermally Stable Heterocuprates with Considerably Improved Reactivity. Some Beneficent Effects of LiBr on Cuprate Reactivity.

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