Thermally stable high molecular weight acyl peroxycarbonic ester

Details Thermally stable high molecular weight acyl peroxycarbonic ester Thermally stable high molecular weight acyl peroxycarbonic ester

1976-06-16

1977-09-27

Lilling, Herbert J.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

260 465VA, 260 75VA, 260453RZ, 260453, 526328, 526330, C08F 434, C08G 6312, C08G 7704, C08F 2010

Patent

active

040513106

ABSTRACT:
Acyl peroxycarbonic esters of the formula ##STR1## in which R is methyl or ethyl, R' is alkyl, and R and R' together have 17 or more carbon atoms. The compounds have unusual thermal stability, together with improved polymerization initiating efficiency. Particularly outstanding efficiency is found in connection with the polymerization of methyl methacrylate.

REFERENCES:
patent: 3108093 (1963-10-01), Pajaczkowski et al.
patent: 3585232 (1971-06-01), Lewis et al.
patent: 3652524 (1972-03-01), Lewis et al.
patent: 3821273 (1974-06-01), D'Angelo
patent: 3903065 (1975-09-01), Norback
patent: 3932372 (1976-01-01), Lewis et al.

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