Thermal barrier coatings having an improved columnar microstruct

Stock material or miscellaneous articles – All metal or with adjacent metals – Composite; i.e. – plural – adjacent – spatially distinct metal...

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428 632, 428633, 428678, 428680, 428660, 428472, 428136, B32B 1504

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058305866

ABSTRACT:
An article having a spallation resistant TBC comprises a metal substrate, such as a high temperature superalloy, and a TBC, such as a coating of yttria stabilized zirconia. The TBC comprises a plurality of plasma-sprayed layers. The TBC has a coherent, continuous columnar grain microstructure, wherein at least one layer has a plurality of continuous columnar grains which have been extended by directional solidification into an adjacent layer. In a preferred embodiment, the coherent, continuous columnar microstructure comprises substantially all of the volume of TBC. A coherent, continuous columnar grain microstructure is also taught wherein at least some of the plurality of coherent, continuous columnar grains which comprise a TBC extend through essentially the entire thickness of the coating. A columnar crack pattern of cracks extending generally normal to the surface of the metal substrate is also developed within TBCs of the present invention in conjunction with the coherent, continuous columnar grain microstructures described.

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Experimental and Theoretical Aspects of Thick Thermal Barrier Coatings for Turbine Applications, V. Wilms, et al., Thermal Spray: Advances in Coatings Tech., Proceedings of the Nat'l Thermal Spray Conf., Orlando, FL; Sep. 1987, pp. 155-166.
Thermal Fatigue of Plasma Sprayed MgO.ZrO2 and ZrO2-6.6Y2O3 Thermal Barrier Coatings, T.A. Taylor et al., Presented at the 84th Annual Meeting American, Ceramic Society, (May 4, 1982) Coatings Service, Engineering Products Division, Union Carbide Div. (20 pages).
AIAA-80-1193 Development of Improved Durability Plasma Sprayed Ceramic Coatings for Gas Turbine Engines, I.E. Sumner, AIAA/SAE/ASME 16th Joint Propulsion Conference (Jun. 30-Jul. 2, 1980) pp. 1-8 and 10-13.

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