Thermal barrier coating system

Stock material or miscellaneous articles – All metal or with adjacent metals – Composite; i.e. – plural – adjacent – spatially distinct metal...

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428656, 428678, 428679, 428680, 428681, 428682, 428683, 428684, C23C 700, C23D 500, B32B 1504

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active

044851510

ABSTRACT:
This invention relates to a high temperature oxidation resistant thermal barrier coating system for a nickel-, cobalt-, or iron-base alloy substrate. An inner metal bond coating contacts the substrate, and a thermal barrier coating covers the bond coating.
NiCrAlR, FeCrAlR, and CoCrAlR alloys have been satisfactory as bond coating compositions where R=Y or Yb. These alloys contain, by weight, 24.9-36.7% chromium, 5.4-18.5% aluminum, and 0.05 to 1.55% yttrium or 0.05 to 0.53% ytterbium. The coatings containing ytterbium are preferred over those containing yttrium.
An outer thermal barrier coating of partially stabilized zirconium oxide (zirconia) which is between 6% and 8%, by weight, of yttrium oxide (yttria) covers the bond coating. Partial stabilization provides a material with superior durability. Partially stabilized zirconia consists of mixtures of cubic, tetragonal, and monoclinic phases.

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Stecura, S., Effects of Compositional Changes on the Performance of a Thermal Barrier Coating System, NASA Tech. Memo., 78976 (1979).
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