Tetrakis(dialkylamino)aromatics and their charge transfer comple

Organic compounds -- part of the class 532-570 series – Organic compounds – Cyclohexadiene having atoms double bonded directly at the 1-...

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552301, 552303, 552308, 556 76, 558403, 558419, 562 84, 562480, 562493, 562607, 564290, 564307, 564308, 564427, 564428, C07C22524, C07C25531, C07C25558

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049994417

ABSTRACT:
Tetrakis(dialkylamino)aromatics Ia to Ic ##STR1## where the radicals A may be identical or different and are n-C.sub.1 -C.sub.6 -alkyl and the radicals R may be identical or different and are hydrogen or C.sub.1 -C.sub.6 -alkyl, and their charge transfer complexes with electron acceptors, and the preparation of Ia to Ic from the corresponding N-unsubstituted amines by alkylation with A'--CHO (where A'.dbd.H or N-C.sub.1 -C.sub.5 -alkyl) and reduction with NaBH.sub.3 CN.
The charge transfer complexes of Ia and Ic are used to prepare electrically conductive polymers.

REFERENCES:
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Borch et al., (1972), J. Org. Chem., 37(10):1637-1674.
Ber., vol. 12 (1879), paper 522-528.
Ber., vol. 12 (1879), paper 2071-2072.
Ber., vol. 20 (1887), paper 328-338.
Ber., vol. 25 (1892), paper 2826-2846.
Angew. Chemie, vol. 98 (1986) paper 460-461.
Karin Elbl et al., Angewandte Chemie, International Edition, vol. 25, No. , Nov. 1986, pp. 1023-1024.

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