Tetrahydropyran-5-one compounds

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2603459R, C07D30906

Patent

active

042461782

ABSTRACT:
A novel class of tetrahydropyran-5-one compounds are provided which are 2-alkoxy- or 2-acyloxy-3,4-dihalogeno-6-alkyl tetrahydropyran-5-ones expressed by the general formula ##STR1## where R.sup.1 is an alkyl group, R.sup.2 is an alkyl or an acyloxy group and X is a halogen atom. The compounds are synthesized by the reaction of a 2-furyl carbinol compound with a halogen in the presence of an alcohol or a carboxylic acid. The compounds are useful as an intermediate for the synthetic preparation of various useful compounds including maltol as a flavor.

REFERENCES:
patent: 4059595 (1977-11-01), Shono et al.
patent: 4082717 (1978-04-01), Brennan et al.
patent: 4126624 (1978-11-01), Brennan et al.
patent: 4150039 (1979-04-01), Harima et al.
Shono et al., Tetrahedron Letters, No. 17, 1363 (1976).
Torii et al., Chemistry Letters, vol. 5, 495 (1976).

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