Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1990-01-02
1991-03-26
Mars, Howard T.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C07C 4106
Patent
active
050031120
ABSTRACT:
A method is disclosed for the preparation of tertiary amyl methyl ether by reaction of methanol and a C-5 olefin over a catalyst comprising an acidic smectite clay, particularly a palladium-modified acidic montmorillonite silica-alumina clay. The method allows for high conversions with yields of up to 93-99 mole %. Further the method is capable of operating efficiently at high LHSVs.
REFERENCES:
patent: 4118425 (1978-10-01), Herbstman
patent: 4193770 (1980-03-01), Chase et al.
patent: 4204077 (1980-05-01), Woods et al.
patent: 4605806 (1986-08-01), Ballantine et al.
patent: 4665220 (1987-05-01), Gregory et al.
Adams et al, Clays and Clay Minerals, vol. 30, No. 2, 129-134, 1982.
Kendrick Cynthia L.
Mars Howard T.
Park Jack H.
Priem Kenneth R.
Texaco Chemical Company
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