Tert.-butoxybutanals, tert.-butoxybutanols, bis-tert.-butoxypent

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568603, 568678, 568599, 568497, 568602, C07C 4702, C07C 4313, C07C 0000

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active

044094027

ABSTRACT:
Tert.-butoxybutanals and tert.-butoxybutanols (I) and bis-tert.-butoxypentanals and bis-tert.-butoxypentanols (II) ##STR1## where R.sup.1 and R.sup.2 are H or C.sub.1 -C.sub.4 -alkyl, one X is --CHO or --CH.sub.2 OH and the others are H.
These compounds, which are valuable as fragrances and for use in organic syntheses are obtained by hydro-formylating the ethers (III) and bis-ethers (IV), respectively, using Rh catalysts. ##STR2##

REFERENCES:
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patent: 3676500 (1972-07-01), Mantell et al.
patent: 4101588 (1978-07-01), Nienburg et al.
patent: 4226637 (1980-10-01), Linden et al.
patent: 4244876 (1981-01-01), Warner
Castro, "J. Organic Chemistry" vol. 26, pp. 4183-4184.

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