Terpene sulfonate hydrotropes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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26050119, 252549, 252558, 2523635, C07C14322

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active

045281440

ABSTRACT:
p-Menthane-7-sulfonic acid and p-menthane-2-sulfonic acid and their alkali metal, alkaline earth metal, ammonium and alkylolammonium salts are disclosed. A method for increasing the solubility of an only partially water-soluble material is presented comprising combining the material in water with the salts of p-menth-6-ene-2-sulfonic acid, p-menth-1-ene-7-sulfonic acid and their saturated derivatives as hydrotropes. p-Menth-6-ene-2-sulfonate salts are prepared from .alpha.-pinene and sulfite or bisulfite salt in the presence of a phase transfer catalyst under free radical conditions.

REFERENCES:
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patent: 2318036 (1943-05-01), Werntz
patent: 3332880 (1967-07-01), Kessler et al.
patent: 3929680 (1975-12-01), Arai et al.
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patent: 4224240 (1980-09-01), Kane et al.
patent: 4283347 (1981-08-01), Kane et al.
Traynor et al., J. Org. Chem., vol. 44, p. 1557, (1979).
Starks, J. Amer. Chem. Soc., vol. 93, p. 195, (1971).

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