Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1978-03-27
1978-11-14
Davis, C.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
2606832, C07C 1102, C07C 522
Patent
active
041255674
ABSTRACT:
Terminal olefin is prepared by bringing together (1) a compound having the formula ##STR1## wherein Cp is a .pi.-cyclopentadienyl radical, R is terminal alkyl and X is an essentially non-interfering monovalent entity, and (2) a mono-olefin having a carbon skeleton different from that of R under reaction conditions to displace R from (1) by (2). This process is especially useful in isomerization of internal olefins to the corresponding terminal olefins.
REFERENCES:
patent: 3173967 (1965-03-01), Brown
Schwartz et al., Agnew Chem. Int. Ed. Engl.; 15, No. 6, pp. 333-340, (1976).
Kidwell Roger L.
Lynch Gary J.
Davis C.
Grattan E. P.
Monsanto Company
Shearin F. D.
Tarter S. M.
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