Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy
Patent
1990-10-10
1992-05-05
Niebling, John
Chemistry: electrical and wave energy
Processes and products
Processes of treating materials by wave energy
204 59R, 570196, C07C 1700
Patent
active
051104253
ABSTRACT:
A terminally chlorinated normal alkane hydrocarbon is produced at high terminal selectivity, by adsorbing a normal alkane into a select zeolite and chlorinating the adsorbed alkane in the zeolite. The zeolite may be of a type having internal channels of diameter slightly larger than that of the alkane, and substantially no internal chambers, and may be selected from the pentasil family of zeolites. The chlorination reaction may be conducted under heating to enhance terminal selectivity even further, in many cases to levels approaching 100%.
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patent: 4971664 (1990-11-01), Turro et al.
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Jacobs, Peter A. et al; "Properties of the End Members in the Pentasil-Family of Zeolites: Characterization as Adsorbents", Zeolites, (1981), vol. 1, pp. 161-168.
Olson, D. H. et al., "Crystal Structure and Structure-Related Properties of ZSM-5", J. Phys. Chem., (1981), vol. 85, pp. 2238-2243.
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Von Ballmoos, R. et al.; "Zoned Aluminum Distribution in Synthetic Zeolite ZSM-5", Nature, (1981), vol. 289, pp. 782-783.
Herron, Norman et al.; "A Highly Selective Zeolite Catalyst for Hydrocarbon Oxidation. A Completely Inorganic Mimic of the Alkane .omega.-Hydroxylases", J. Am. Chem. Soc., (1987), vol. 109, pp. 2837-2839.
Herron, N. et al.; "Selective Catalytic Oxygenation of Hydrocarbons with Molecular Oxygen at Room Temperature--a Completely Inorganic Mimic of Monoxygenase Enzymes," Preprint, Symposium on Advances in Oil Shale Technology, vol. 32, No. 1, (1987), pp. 200-204.
Fehlner James R.
Turro Nicholas J.
Inrad, Inc.
Marquis Steven P.
Niebling John
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