Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy
Patent
1988-07-13
1990-11-20
Niebling, John F.
Chemistry: electrical and wave energy
Processes and products
Processes of treating materials by wave energy
204 59R, 570196, C07C 1700
Patent
active
049716646
ABSTRACT:
A terminally chlorinated normal alkane hydrocarbon is produced at high terminal selectivity, by adsorbing a normal alkane into a select zeolite and chlorinating the adsorbed alkane in the zeolite. The zeolite may be of a type having internal channels of diameter slightly larger than that of the alkane, and substantially no internal chambers, and may be selected from the pentasil family of zeolites. The chlorination reaction may be conducted under heating to enhance terminal selectivity even further, in many cases to levels approaching 100%.
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Herron, Norman et al.; "A Highly Selective Zeolite Catalyst for Hydrocarbon Oxidation. A Completely Inorganic Mimic of the Alkane .omega.-Hydroxylases", J. Am. Chem. Soc., (1987), vol. 109, pp. 2837-2839.
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Fehlner James R.
Turro Nicholas J.
Inrad, Inc.
McAndrews Isabelle R.
Niebling John F.
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