Teritary amine containing antonic initiators used in preparing p

Organic compounds -- part of the class 532-570 series – Organic compounds – Unsubstituted hydrocarbyl chain between the ring and the -c-...

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540465, 544 64, 544 4, 544225, 546 11, 548101, 556 1, 502157, C07D22304, C07D29504

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055678157

ABSTRACT:
An anionic initiator system formed by the reaction product of: (1) an organolithium compound with (2) the reaction product of (a) a secondary amine and (b) diisopropenyl benzene, initiates polymerization to produce a polymer containing tertiary amine functional sites incorporated at the head of the polymer chain. A subclass of these polymers can be compounded to exhibit reduced hysteresis over conventionally prepared polymers.

REFERENCES:
patent: 5039814 (1991-08-01), Shuman et al.
patent: 5153159 (1992-10-01), Antkowiak et al.
Katritzky, A. R. Handbook of Heterocyclic Chemistry (Pergemon Press, Oxford), pp. 148 and 151 (1985).

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