Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...
Reexamination Certificate
1999-11-24
2002-07-16
Lipman, Bernard (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Mixing of two or more solid polymers; mixing of solid...
C525S330300, C525S330500, C525S330600, C525S379000, C525S388000
Reexamination Certificate
active
06420490
ABSTRACT:
FIELD OF INVENTION
This invention relates to a process for producing telechelic functionalized polymers by ozonation degradation of diene polymers. More particularly, this invention relates to the synthesis of fully saturated mono-ol polymers and telechelic polymers containing reactive endgroups and polar midblocks.
BACKGROUND OF THE INVENTION
Functionalized anionically polymerized polymers of conjugated dienes and other monomers wherein the functionalization is terminal and/or internal are known. Particularly, U.S. Pat. No. 5,393,843 describes polybutadiene polymers having terminal functional groups. One of the methods described for making such polymers involves anionic polymerization utilizing a dilithium initiator such as the adduct derived from the reaction of m-diisopropenylbenzene with two equivalents of s-BuLi. Monomer is added to the initiator in hydrocarbon solution and anionic living polymer chains grow outwardly from the ends of the dilithium initiator. These polymers are then capped to form functional end groups as described in U.S. Pat. Nos. 4,417,029, 4,518,753, and 4,753,991. Of particular interest herein are terminal hydroxyl, carboxyl, sulfonate, and amine groups.
The aforementioned patent describes one method of making functionalized polymers. In order to get saturated functionalized polymers, a hydrogenation step is necessary. It would be advantageous to be able to produce such polymers without the necessity of the hydrogenation step. Also, it would be advantageous to be able to produce such polymers which contain polar functionality in the midblock or interior of the polymer. The present invention provides a method for accomplishing these desired results.
SUMMARY OF THE INVENTION
In one aspect of the present invention, a fully saturated monohydroxylated polyolefin polymer is produced by (a) treating an unsaturated polydiene polymer with ozone to degrade the polymer to polymer segments which have an aldehyde or ketonic group at the chain terminus; and (b) selectively reducing the aldehyde or ketone end group by treatment with hydrogen in the presence of a hydrogenation catalyst such as Raney nickel to form a polymer which has hydroxyl groups on the chain ends as shown in the following generic formula where R is hydrogen, methyl, or higher alkyl:
If R═H, then both ends have a primary hydroxyl group. In a preferred embodiment, the unsaturated polydiene polymer is butyl rubber which is a copolymer of polyisobutylene and isoprene or polyisobutylene and butadiene.
In another aspect of the present invention, a low molecular weight, telechelic polymer containing polar internal functionality is produced by (a) treating a copolymer of a polar alpha olefin and a conjugated diene with ozone to degrade the copolymer and form polymer segments which have aldehyde or ketone groups at the chain ends, wherein the copolymer has a random distribution of predominantly 1,4-diene double bonds and the pendant functional groups of the polar alpha olefin are stable to ozone, and (b) further reacting the aldehyde or ketone end groups to provide terminal functionality. The terminal functionality which can be provided includes carboxylic acid groups, primary hydroxyl groups, and amide groups.
DETAILED DESCRIPTION OF THE INVENTION
Polyolefin-co-polydiene polymers which are used as the starting polymer in the process of the present invention are well known. They can be produced by anionic polymerization of conjugated diene hydrocarbons with lithium initiators as described in U.S. Pat. Nos. 4,039,593 and Reissue 27,145 which are herein incorporated by reference. In this case, the resultant polymer must be partially hydrogenated. These polymers can also be produced by cationic polymerization using Lewis acid initiators. Anionic polymerization commences with a monolithium, dilithium, or polylithium initiator which builds a living polymer backbone at each lithium site.
Almost any polyolefin-co-polydiene polymer can be utilized in the present invention. The main requirement is that there be some C—C double bonds in the backbone of the polymer which are subject to degradative attack by ozone. Such polymers may contain polar internal functionality as described below. Thus, polymers which can be used in the present invention include butyl rubber, which is a copolymer of polyisobutylene (PIB) and isoprene or butadiene, partially saturated polyisoprene, partially saturated polybutadiene, copolymers of these dienes, polymers of other conjugated dienes, copolymers of conjugated dienes with styrene and styrene derivatives, and copolymers of conjugated diene with acrylic monomers. In order to obtain a telechelic polymer containing polar internal (ofttimes referred to as midblock) functionality, the starting polymer must be a copolymer of a polar alpha olefin and a conjugated diene. The polar comonomer in this copolymer is preferably an acrylate or methacrylate polymer but may also be acrylamide or similar structure:
where Y═NR
2
, NRH, NH
2
, ester, or halide. For this copolymer, it is important that it contain a random distribution of predominantly 1,4-diene double bonds (where the degradation attack will take place), that the polar functional groups be pendant and inert to ozone, and that the molecular weight of the copolymer be high enough to afford an average functionality on the final polymer of at least 2.0. This means that the number average molecular weight of the precursor polymer should be at least 25,000, preferably 100,000. However, if polymers with lower functionality are desired, a lower number average molecular weight polymer can be used.
The starting polymers described above may be subjected to degradative ozonation through the use of a gas consisting wholly of ozone but more generally through the contacting of these polymers with gases such as air or oxygen containing up to 15 percent by weight of ozone. Mixtures of oxygen and ozone are preferred from a practical standpoint. The starting polymers are dissolved in a suitable solvent such as carbon tetrachloride, the straight or branched chain aliphatic hydrocarbons such as normal hexane, normal heptane, isohectane, isopentane, or any other non-reactive solvent for the polymer which is inert to ozone under the conditions of this invention. Generally, for convenience, the concentration of the polymer in the solvent will range from about a 1 percent to about 30 percent by volume, preferably about 10 percent to about 20 percent by volume. Into this solution, there is bubbled a stream of an ozone-containing gas while maintaining the temperature of between −80° C. and 85° C., preferably between −50° C. and 50° C., especially when the solvent is a hydrocarbon. Pressures of from atmospheric up to 500 psig, preferably from atmospheric up to 100 psig, may be employed. The higher pressure is used where the solvent would normally volatilize if temperatures in the upper range of those specified are employed. The time for carrying out the reaction may range from about 5 minutes to about 15 hours, preferably between 15 minutes to 2 hours is sufficient. U.S. Pat. No. 3,392,154, which is herein incorporated by reference, describes the ozonolysis of polymers of the type described herein. The conditions specified in the patent may generally be used in this invention.
The reaction conditions during ozonation are correlated so as to achieve, as far as possible, a polymeric ozonide which, on ozonolysis, will yield a polymer having the desired molecular weight and preferably a polymer in which each molecule has attached at each chain end a functional group. The primary decomposition of the ozonide of this type of polymer is believed to give rise to the formation of aldehyde or ketone functional groups at the chain ends.
The decomposition of the ozonides prepared as described above may be carried out in a number of ways. The ozonides, still in the solvent solution, may be subjected to small quantities of hydrogen, using a hydrogenation catalyst, or to an active hydrogen-containing compound such as water, tertiary amines such as pyridi
KRATON Polymers U.S. LLC
Lipman Bernard
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