Tabular grain silver halide emulsions, a method for their prepar

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430569, 430603, 430605, G03C 1005, G03C 1035

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active

057260060

ABSTRACT:
A photosensitive emulsion is disclosed comprised of a dispersing medium and silver halide grains containing at least 80 mole percent bromide, based on silver, wherein at least 50% of the projected area of said silver halide grains is accounted for by tabular grains free of twin planes having {100} parallel major faces, said emulsion being chemically sensitized and having a reciprocity failure of less than 35 sensitivity units between exposures of respectively 10.sup.-5 seconds and 100 seconds. The emulsion can be employed as a latent image forming emulsion in a photographic element.
The emulsion can be prepared by a process preparing a silver bromide photosensitive emulsion, comprising the following essential steps: (a) a nucleation step whereby a fine-grain emulsion with a pAg of between 4 and 6.5 and a pH of between 2 and 5 is precipitated, while maintaining, at the start of the nucleation and for a short time, a stoichiometric excess concentration of silver corresponding to a pAg of less than 5, and (b) a physical ripening step, at a pAg of between 8 and 9.5 and a pH of between 6 and 8.

REFERENCES:
patent: 4063951 (1977-12-01), Bogg
patent: 4386156 (1983-05-01), Mignot
patent: 5565314 (1996-10-01), Nakatsu et al.

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