Tabular grain emulsions with sensitization enhancements

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430604, 430605, G03C 1035, G03C 109

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active

055761712

ABSTRACT:
A chemically and spectrally sensitized tabular grain emulsion is disclosed including tabular grains (a) having {111} major faces, (b) containing greater than 70 mole percent bromide and at least 0.25 mole percent iodide, based on silver, (c) accounting for greater than 90 percent of total grain projected area, (d) exhibiting an average equivalent circular diameter of at least 0.7 .mu.m, and (f) exhibiting an average thickness in the range of from less than 0.3 .mu.m to at least 0.07 .mu.m.
It has been observed that photographic performance is enhanced when surface chemical sensitization sites include epitaxially deposited silver halide protrusions forming epitaxial junctions with the tabular grains, the protrusions (a) being located on up to 50 percent of the surface area of the tabular grains, (b) having a higher overall solubility than at least that portion of the tabular grains forming epitaxial junction with the protrusions, (c) forming a face centered cubic crystal lattice, and (d) containing a speed enhancing dopant selected to provide shallow electron trapping sites.

REFERENCES:
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patent: 4471050 (1984-09-01), Maskasky
patent: 4814264 (1989-03-01), Kishida et al.
patent: 5462849 (1995-10-01), Kuromoto et al.
patent: 5494789 (1996-02-01), Daubendiek et al.
patent: 5503970 (1996-04-01), Olm et al.
patent: 5503971 (1996-04-01), Daubendiek et al.
patent: 5518872 (1996-05-01), King et al.
Research Disclosure vol. 367, Nov. 1994, Item 36736.

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