Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – Solid – shaped macroscopic article or structure
Reexamination Certificate
1999-11-24
2002-03-12
Douyon, Lorna M. (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
Solid, shaped macroscopic article or structure
C510S224000, C510S294000, C510S298000, C510S361000, C510S441000, C510S509000
Reexamination Certificate
active
06355607
ABSTRACT:
The present invention relates to the field of tablets, especially those adapted for use with laundry, i.e. washing clothes etc., and automatic dishwashing.
Some tablets are designed to dissolve or disintegrate in a liquid, for example water, before use in order to provide a solution or suspension of active ingredients. When such tablets need to be dissolved or disintegrated, problems often arise due to the rate of dissolution and disintegration of the tablets. These problems are particularly severe in the field of detergent tablets where it is desirable to rapidly deliver active ingredients, especially surface active agents (surfactants). Furthermore these problems are particular severe when detergent tablets are use for hand-washing, as opposed to machine washing, because very little agitation is provided by hand.
“Detergents Manufacture” by Marshall Sittig, published by Noyes Data Corp. 1976, says on page 340 that “the production of [detergent] tablets requires very special measures as regards selecting the components of the tablet and working up these components into the final detergent tablet. Consequently the production of detergent tablets is a complex matter. It involves even more than the mere selection of the components or the compression of a particular detergent composition into a tablet: the tablet must be capable of withstanding shocks of packing, handling and distribution without crumbling. In other words the tablet must be strong. Besides the tablet must have a satisfactory rate of disintegration when put in water. The tablets known so far have generally shown too long a disintegration time, in favour of their strength, or they have had a very low strength, in favor of their disintegration time.”
One of the approaches known in the prior art to try to address this problem is the use of acetate salt to improve the dissolution rate of detergents compressed in the form of tablets. For instance:
EP-A-0 002 293, published on Jun. 13, 1979, discloses detergent tablets containing hydrated salt. The preferred hydrate salt is a mixture of sodium acetate trihydrate and sodium metaborate tetrahydrate.
Another approach known in the prior art to try to address this problem is to use effervescent aids to improve tablet disintegration:
CA-A-2 040 307, discloses laundry detergent tablets comprising anionic surfactants mixed with sodium carbonate and citric acid.
The object of the present invention is to provide tablets which have a rapid rate of disintegration and dissolution, and which are at the same time sufficiently strong to withstand shocks of packing, handling and distribution without crumbling. A particular object of the present invention is to is to provide tablets which rapidly deliver active ingredients, especially surface active agents into solution, especially during a laundry process with little mechanical agitation, such as handwash. It is a further object of the invention that tablets, when used in a domestic, front-loading washing machine,will leave little or no visible residue in the window of the machine during the wash cycle.
SUMMARY OF THE INVENTION
The object of the invention is achieved by providing a tablet comprising a combination of a means for providing effervescency upon contact with water, as well as a soluble salt selected from the group consisting of acetate, urea, and mixtures thereof. The means for providing effervescency upon contact with water preferably comprises citric acid and a carbonate salt, such as a bicarbonate salt.
Preferably the acetate or urea is present at a level of from 1% to 50% by weight of the tablet. Preferably also the tablet further comprises at least 5% by weight of a surface active agent.
DETAILED DESCRIPTION OF THE INVENTION
Any means for providing effervescency upon contact with water may be used in the present invention. Some suitable examples are described by R. Mohrie in“Pharmaceutical dosage forms: tablets volume 1, Ed H. A. Lieberman et al”, published in 1989.
The most common means for providing effervescency is an acidification component and a carbonate salt. Upon contact with water the two components react to yield carbon dioxide gas. Preferred acidification components include inorganic and organic acids including for example carboxylate acids such as citric and succinic acids, polycarboxylate acids such as polyacrylic acid and also acetic acid, boric acid, malonic acid, adipic acid, fumaric acid, lactic acid, glycolic acid, tartaric acid, tartronic acid, ascorbic acid, phthalic acid, stearic acid, gluconic acid, malic acid, maleic acid, their derivatives (e.g. acid anhydrides such as succinic anhydride, citric anhydride), ethane, 1-hydroxy, 1,1 diphosphonic acid (HEDP) and any mixtures thereof. A highly preferred acidification acid is citric acid which has the advantage of providing builder capacity to the wash solution, leading to better soil removal. Other suitable acid sources are acid salts such as sodium dihydrogen phosphate (monosodium phosphate), disodium dihydrogen pyrophosphate (sodium acid pyrophosphate), acid citrate salts (e.g. sodium dihydrogen citrate and disodium hydrogen citrate), sodium acid sulfite (sodium bisulfite) and mixtures thereof. Bicarbonates, particularly sodium bicarbonate are also useful acidification agents in cases where the carbonate salt used is one which is more alkaline than sodium bicarbonate.
The term carbonate salt herein is used to mean any salt which is capable of releasing carbon dioxide when reacted with an acid. Preferred carbonate salts include sodium bicarbonate, sodium carbonate, potassium bicarbonate and potassium carbonate, sodium sesquicarbonate, sodium glycine carbonate, L-lysine carbonate, arginine carbonate, amorphous calcium carbonate and mixtures thereof.
Other suitable means for providing effervescency are anhydrous sodium perborate or effervescent perborate (this latter is sodium perborate monohydrate or tetrahydrate heated to drive their water off).
Soluble salts useful in the present invention include salts such as sodium acetate, ammonium acetate, calcium acetate, potassium acetate, rubidium acetate, urea and mixtures thereof.
The present invention provides a tablet which easily and rapidly disintegrates upon contact with water, even with a small amount of agitation, such as occurs in hand-wash. Once disintegrated the tablet fragments easily and rapidly dissolve in the water. Without wishing to be bound by theory the mechanism behind the synergistic effect between the acetate and the means for providing effervescency could be as follows:
(i) acetate salts are highly water soluble material which dissolve rapidly when brought into contact with water. Its rapid dissolution leads to a tablet with a porous structure which is easily disintegrated;
(ii) the disintegrated tablet exposes the means for providing effervescency to the water, and the gas generated acts to disrupt the normal tablet structure, allowing contact of more tablet surfaces with wash water, which promotes dissolving.
The combination of these two different modes of tablet disruption induces a higher level of disintegration than that which could be expected when either of these mechanisms is used alone.
Optionally the tablets of the present invention may also be provided with a coating. The coating should allow the tablets to be handled in normal use with breaking. Tablets which might otherwise be too fragile may be provided with a coating for this purpose.
Particularly preferred coatings materials are fatty acids, adipic acid and C8-C13 dicarboxylic acids, fatty alcohols, diols, esters and ethers. Preferred fatty acids are those having a carbon chain length of from C12 to C22 and most preferably from C18 to C22. Preferred dicarboxylic acids are adipic acid (C6), suberic acid (C8), azelaic acid (C9), sebacic acid (C10), undecanedioic acid (C11), dodecanedioic acid (C12) and tridecanedioic acid (C13). Preferred fatty alcohols are those having a carbon chain length of from C12 to C22 and most preferably from C14 to C18. Preferred diols are 1,2-octadecanediol and 1,2-hexadecanediol. Pr
Rahman Sonia
Van Dijk Paul Irma Albertus
Douyon Lorna M.
Dressman Marianne
Miller Steven W.
The Procter & Gamble & Company
William Zerby Kim
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