T-Alkyl peresters of t-hydroperoxides catalysts for polymerizati

Details T-Alkyl peresters of t-hydroperoxides catalysts for polymerizati T-Alkyl peresters of t-hydroperoxides catalysts for polymerizati

1977-04-28

1977-12-13

Lilling, Herbert J.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526228, 526319, 526344, 526346, 526352, C08F 428, C08F 1406, C08F11002

Patent

active

040630137

ABSTRACT:
Novel tertiary alkyl peresters of tertiary hydroperoxides are used as polymerization initiators wherein the peresters are characterized by the tertiary alkyl group of the acid moiety having at least two alkyl groups of two or more carbon atoms and the tertiary alkyl group of the hydroperoxide has at least five carbon atoms. Typical is the polymerization of certain vinyl monomers such as vinyl chloride.

REFERENCES:
patent: 3022282 (1962-02-01), Marous et al.
patent: 3446831 (1969-05-01), Mageli et al.
patent: 3687867 (1972-08-01), Lewis et al.
patent: 3726847 (1973-04-01), Lewis et al.
patent: 3763128 (1973-10-01), Lewis et al.

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