Liquid purification or separation – Processes – Utilizing electrical or wave energy directly applied to...
Reexamination Certificate
2000-12-12
2003-01-07
Hoey, Betsey Morrison (Department: 1724)
Liquid purification or separation
Processes
Utilizing electrical or wave energy directly applied to...
C210S760000, C210S192000, C210S198100, C422S186120, C422S186140, C422S186190, C422S186200
Reexamination Certificate
active
06503402
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of Invention
This invention relates generally to systems and methods for treating irrigation water and, more specifically, to a system and method for treating irrigation water utilizing a high concentration ozone generation apparatus.
2. Background of the Invention
The use of ozone, an unstable molecule comprised of three atoms of oxygen (O
3
) having a high oxidation potential, to purify water and air is well known. It was used to purify drinking water by the latter part of the 1800's, and today is used for this purpose by most major U.S. cities. Ozone has also been utilized for the purification of other types of water, including irrigation water, as well as waste water and cooling tower water. Still further, ozone has been used for purifying the air in food storage facilities going back at least as far as 1909.
The basic principles underlying the use of ozone generation are well established. Clean, dry air consists of approximately 78 percent nitrogen gas (N
2
), approximately 21 percent oxygen gas (O
2
), and less than one percent of hydrogen (H
2
) and other gasses. When air (referred to as the “feed gas” in this context) is irradiated using either an ultraviolet source or corona discharge (the acceleration of electrons between two electrodes, separated by a dielectric material, to collide with a feed gas passed therebetween), some of the O
2
molecules are split to form two short-lived oxygen atoms. These oxygen atoms combine, almost instantaneously, with uncleaved oxygen molecules to form ozone. Ozone is not the only product of what is generally referred to herein as an ozonation process; i.e., the irradiation of a feed gas to create ozone and other new compounds. The bombarding of the feed gas with electrons causes the all of the component gasses—and not just the oxygen to rearrange—forming a number of beneficial molecular combinations in addition to ozone. These rearranged molecules include nitrates, nitrites, nitrogen oxides, nitric acid, nitrogen based acids, hydrogen peroxide, hydroperoxide, and hydroxyl radicals (NO, NO
2
, NO
3
, N
2
O, N
2
O
5
, HNO
2
, HNO
3
, O, H, OH, HO
2
, H
2
O
2
).
Ozone and certain of the other atoms and molecules formed as a result of ozonation (including hydrogen peroxide and hydroxyl radicals) have a number of beneficial uses in the areas of disinfection and odor elimination—and are useful in the treatment of irrigation water, as well as drinking water, waste water, cooling tower water, stored foods, etc. Certain of the nitrogen containing molecules produced as result of this process, including in particular nitrates and nitric acid, can be used beneficially to treat irrigation water and to thereby act as a fertilizer and assist plant growth.
Ultraviolet radiation is disfavored as a method for generating ozone, due to the inability to produce high quantities of ozone at a relatively low cost in this fashion. As a result, most commercial ozone production is accomplished using a corona discharge type of ozone generator.
However, there are numerous problems with prior art corona discharge ozone generators, and thus limitations on their suitability for use in a system and method for treating irrigation water. Thus, when the feed gas is passed between the electrodes, water or dust present in the feed gas attach themselves to the dielectric surrounding the cathode. These spots tend to attract electrons, with the result that hot spots are formed on the surface of the dielectric—leading eventually to the burning through of the dielectric and consequent failure of the generation apparatus. In the commercial area, ozone generators require constant servicing and, indeed, rebuilding, because of such problems. In the City of Los Angeles, for example, high concentration ozone generators used to treat the city,s drinking water are presently required to be rebuilt after approximately ten days of use—a rate that is plainly undesirable. Moreover, prior art devices do not permit the ready manipulation of the ozonation products, for example to produce more ozone and less nitrogen-containing compounds or more nitrogen-containing products and less ozone. This type of manipulation is particularly desired in a system and method for treating irrigation water.
U.S. Pat. No. 4,954,321, issued to the applicant herein, illustrates a plasma corona discharge apparatus, representing an improvement upon the basic corona discharge process. Generally, a plasma corona discharge apparatus is similar to a non-plasma apparatus, except that in a plasma apparatus, an inert gas is inserted into an elongated, insulated, sealed cathode, into which electrons are fired for the ozonation process. That gas performs two functions. First, it generally precludes the formation of hot spots and resulting dielectric burn-through and generator failure through a convection process. In this regard, the inert gas, which has become a plasma by virtue of the electrons passing therethrough, becomes attracted to a water or dust spot, the gas becomes heated and then rises away from the hot spot, to be replaced by gas having a lower temperature. This results in a relatively constant movement of the gas and substantially reduces overheating and/or apparatus failure attributable to the formation of stable hot spots.
The second function of the inert gas is to directly assist in the efficiency of the ozonation process. In this regard, upon the firing of electrons from an electron gun into the inert gas, a plasma is formed within the cathode (i.e., on the inside of the dielectric), and also outside of the dielectric. The passage of electrons though this plasma and into the feed gas causes oxygen disassociation and reformation as ozone at an improved rate over non-plasma devices.
However, even the plasma device illustrated in U.S. Pat. No. 4,954,321, while more reliable than prior art devices, suffers from important limitations and deficiencies. For example, the energy produced by the electron gun firing into the cathode is concentrated near the electron gun, and gradually dissipates over the length of the electrode. This results in a decrease in the effectiveness of this particular prior art apparatus in treating the feed gas, and thus in the production of a lower concentration of ozone than is possible if the energy level could be maintained constant throughout the length of the cathode.
A need therefore existed for an improved system and method for treating irrigation water, based on an ozone generator apparatus and method capable of reliably generating high concentrations of ozone (and other ozonation products) suitable for use in such treatment. The improved system and method should provide for the maintenance of a relatively constant energy level throughout the length of the energy-producing electrode, so as to provide more efficient production of ozonation products. The improved system and method should also provide for the efficient adjustment of the products of ozonation, so that ozone or nitrogen-containing products can be favored. The present invention satisfies these needs and provides other, related, advantages.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide an improved system and method for treating irrigation water with ozone and other atoms and molecules formed from the bombardment of a feed gas with electrons.
It is an object of this invention to provide an improved system and method for treating irrigation water with ozone and other atoms and molecules formed from the bombardment of a feed gas with electrons, wherein the system and method have a reduced risk of failure as compared to prior art systems and method based on corona discharge apparatuses.
It is a further object of this invention to provide an improved system and method for treating irrigation water with ozone and other atoms and molecules formed from the bombardment of a feed gas with electrons capable of producing a higher concentration of ozone than prior art systems and methods based on corona discharge apparatuses by, among other things, providing f
Hoey Betsey Morrison
Nytrox !, Inc.
Weiss Harry M.
Weiss Jeffrey
Weiss, Moy & Harris P.C.
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