System and method for trace species detection using cavity...

Optics: measuring and testing – For light transmission or absorption – Of fluent material

Reexamination Certificate

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Reexamination Certificate

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10987637

ABSTRACT:
This invention provides a system and method that enables the use of incoherent light sources, such as light emitting diodes, to provide for the detection of gaseous species which exhibit broadband absorption features (e.g., nitrogen dioxide and the halogen gases). The light emitting diode (LED) is an ideal light source for such an arrangement in that it can be modulated at high frequencies (allowing for omission of external modulation equipment) and provides sufficient illumination within a reasonably narrow wavelength band as compared to, for instance, an incandescent light source. A further advantage of a LED as a light source compared to alternatives such as a gas discharge or arc lamp is that the light output of the LED is highly stable, limited by the stability of the current source used to drive it. Use of a confocal or near-confocal resonant optical cavity maximizes coupling of the light source to the cavity.

REFERENCES:
patent: 5528040 (1996-06-01), Lehmann
patent: 5793545 (1998-08-01), Monfre et al.
Ball et al.; “Broadband cavity enhanced absoprtion spectroscopy using light emitting diodes”;Oct. 5, 2004; Chemical Physics Letters 398 (2004) 68-74.
Engeln et al., “Phase shift cavity ring down absorption spectroscopy,” Chemical Physics Letters, Jun. 14, 1996, pp. 105-109, 262 (1996), Elsevier Science B.V.
Scherer et al., “Cavity Ringdown Laser Absorption Spectrosopy: History, Development, and Application to Pulsed Molecular Beams,” Chemical Review, 1997, pp. 25-51, 97 (1997), American Chemical Society.
Hamers et al., “Fourier transforms phase shift cavity ring down spectroscopy,” Chemical Physics Letters, Sep. 9, 2002, pp. 237-243, 365 (2002), Elsevier Science B.V.
Fiedler et al., “Incoherent broad-band cavity-enhanced absorption spectroscopy,” Chemical Physics Letters, Jan. 16, 2003, pp. 284-294, 371 (2003), Elsevier Science B.V.
Steven S. Brown, “Absorption Spectroscopy in High-Finesse Cavities for Atmospheric Studies,” Chemical Review, Mar. 6, 2003, pp. 5219-5238, 103 (2003), American Chemical Society.
Ball et al., “Broad-Band Cavity Ring-Down Spectroscopy,” Chemical Review, Apr. 7, 2003, pp. 5239-5262, 103 (2003), American Chemical Society.

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