Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing
Reexamination Certificate
1999-06-25
2001-09-11
Le, Hoa T. (Department: 1773)
Chemistry of inorganic compounds
Phosphorus or compound thereof
Oxygen containing
C423S311000, C428S330000, C428S402000, C521S149000
Reexamination Certificate
active
06287530
ABSTRACT:
TECHNICAL FIELD
The present invention relates to an additive for synthetic resins comprising particles of a specific form of petaloid porous hydroxyapatite, and a synthetic resin composition blended with this additive. The purpose of the present invention is to provide an additive for synthetic resins being capable of giving a synthetic resin film excellent in anti-scratch property and anti-blocking property, a synthetic resin fiber excellent in dyeability, and a synthetic resin composition excellent in transparency, and a synthetic resin composition blended therewith.
BACKGROUND ART
Synthetic resins are widely used in various industrial fields. Among the synthetic resins, an industrially manufactured polyester, especially polyethyleneterephthalate (hereinafter referred to as PET) has superior physical and chemical characteristics and is used as fibers, films, and other molded articles. For example, in a film area, the polyester is used for magnetic tapes such as audiotapes and videotapes, condensers, photographs, wrappings, OHP, pre-paid cards and so on. In the polyester film, slipperiness and anti-shavingness are main elements that control workability in a manufacturing step or a processing step of the film in various uses, and a quality of a product. In a case where a magnet layer is coated on a surface of the polyester film so as to use as a magnetic tape, if the slipperiness and anti-shavingness of the film are not sufficient, a friction between coating rolls and the surface of the film becomes large, thereby causing a severe abrasion of the surface of the film, and in an extreme case, resulting in wrinkles and scratches on the surface of the film. Even after processing the film into a tape such as audiotapes, videotapes and computer-tapes by slitting the film which is coated with the magnetic layer, an extreme friction between the surface of the film and many guides or a reproduction head will occur during operations such as drawing out of the tape from a reel or cassette, winding the tape and so on. This extreme friction causes scratches or strain, and the shaving of the surface of the polyester film deposits white powder, and results in a lack of magnetic recording signal, namely, drop-out.
For lowering a friction coefficient of the polyester, many methods for improving slipperiness of the surface of the molded articles are proposed by incorporating inorganic fine particles into polyester so as to give minute and appropriate roughness to the surface of the molded articles of the polyester. However, since affinity between the fine particles and the polyester is not sufficient, both transparency and anti-abrasion property of the film are not satisfactory.
In case of a polyolefin, the polyolefin is widely used in various industrial fields. Especially, a polyolefin film such as a polypropylene film is the most widely used as various wrapping materials. Since it is known that such kind of the polyolefin film is adhesive, the polyolefin film tends to cause blocking. For this reason, workability in a process for manufacturing or processing of the film becomes worse. Furthermore, in a case where the film is used in packaging or wrapping, troubles such as less workability in opening the package or wrapping tend to occur. Therefore, in general, an anti-blocking treatment is done on this kind of film. As an anti-blocking agent, a finely powdered silicic acid, zeolite, calcium carbonate and kaolin clay are typically known and used.
On the other hand, the polyolefin film requires, as qualitative characterics, superior transparency and good anti-scratch property (For example, the surface of the film is less scratched when the surfaces of the films are contacted with each other.). However, the transparency and the anti-scratch property are contrary to the anti-blocking property. For example, in order to improve the anti-blocking property of the polyolefin film, if a large amount of the anti-blocking agent is used, the anti-scratch property and the transparency become poorer as an amount of the anti-blocking agent to be added is increased. Therefore, as the additive to improve the anti-blocking property, the anti-scratch property and the transparency of the film to a satisfactory level, the conventional inorganic powder was far from satisfaction.
In case of the conventional kaolin clay, since the particle shape of the kaolin clay has a plate-like structure, when it is used as an anti-blocking agent of the polyolefin film, it can not form roughness on the surface of the polyolefin film in a satisfactory level. Therefore, a large amount of kaolin clay is required to obtain a satisfactory level of anti-blocking property. As a result, only polyolefin film having insufficient transparency could have been obtained.
In case of the finely powdered silicic acid, since the main particles of the silicic acid is extremely minute, a polyolefin film with a satisfactory level of transparency and anti-scratch property can be obtained. However, since the silicic acid cannot form sufficient roughness on the surface of the polyolefin film, a polyolefin film having a satisfactory level of anti-blocking property could not have been obtained even though a large amount of silicic acid was used.
In case of the powdered zeolite, a polyolefin film that has good transparency and anti-blocking property can be obtained when compared to a film containing the kaolin clay or the finely powdered silicic acid. However, a film with good anti-scratch property cannot be obtained. Moreover, since the zeolite is known to have crystalline water, it may cause defective products due to bubbling formed by the crystalline water which is released from the zeolite by heating in a process of molding a synthetic resin or making a film. If the zeolite is heated to remove so called zeolite water so as to make an activated zeolite which does not have crystalline water, it readsorbs water easily. Therefore, it is substantially impossible to remove an influence of the water in a process for film formation.
Furthermore, in case of the calcium carbonate, since the calcium carbonate does not have crystalline water, there is no bubbling due to a release of the crystalline water. However, since the calcium carbonate inherently has a strong aggregation tendency, the calcium carbonate tends to form secondary large particles which are formed by aggregation of many primary particles. Therefore, the calcium carbonate has problems to be solved as a good anti-blocking agent for a polyolefin film with a good anti-blocking property, transparency and anti-scratch property.
Moreover, in case of a synthetic fiber, it is considered to improve dyeability of a polyester fiber which is difficult to dye that roughness is formed on the surface of fiber. However, when importance is attached to the dyeability, the strength of a fiber itself lowers to thereby damage excellent properties inherent to the polyester fiber.
In view of the above facts, after extensive and intensive studies on an additive for synthetic resins which can give a good anti-blocking property, good transparency and good anti-scratch property to synthetic resins represented by polyesters or polyolefins, especially a film or a fiber thereof and which has a good affinity to the synthetic resin, and further on a synthetic resin composition containing the additive, the present inventors have found out that particles of petaloid porous hydroxyapatite having a specific particle composition, specific particle diameter and degree of dispersion thereof and specific surface area have functions as the intended additive for synthetic resins, and that a synthetic resin composition blended with this additive can attain the intended purpose, and thus accomplished the present invention.
DISCLOSURE OF INVENTION
The present invention is, in a first aspect, directed to an additive for synthetic resins which comprises particles of petaloid porous hydroxyapatite represented by a chemical formula Ca
10
(PO
4
)
6
(OH)
2
, said particles satisfying the following formulas (a)-(d):
0.1≦dx1≦20(&mgr;m) &emsp
Aoyama Mitsunobu
Minayoshi Shiro
Nishioka Hidehiko
Takiyama Shigeo
Armstrong Westerman Hattori McLeland & Naughton LLP
Le Hoa T.
Maruo Calcium Company Ltd.
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