Synthetic method of soluble PPV derivatives having two silyl gro

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528 40, 528 43, C08G 7760

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active

061179655

ABSTRACT:
There is disclosed a synthetic method of mixing a soluble poly(1,4-phenylenvinylene) (PPV) derivative in which two silyl groups are substituted, and an electroluminescent device using the same. In the poly[2,5-bis(dimethyloctylsilyl)-1,4-phenylenvinylene] (BDMOS-PPV) according to the present invention, the final polymer is easily dissolved in common organic solvents and shows a measured absolute PL quantum efficiency of 60% much higher than that of the conventional PPV having 25%, thus making it possible to be applied as material of an electroluminescent device. Also, it provides an outstanding advantage that it can be applied to a flexible light-emitting device.

REFERENCES:
patent: 5247190 (1993-09-01), Friend et al.
patent: 5691433 (1997-11-01), Kotani et al.
J. H. Burroughes, et al., "Light-Emitting Diodes Based on Conjugated Polymers", Letters to Nature, pp. 539-541, Oct. 11, 1990.
Do-Hoon Hwang, et al., Green Light-Emitting Diodes from Poly(2-Dimethyloctylsilyl-1,4-Phenylenevinylene), Chem. Commun., pp. 2241-2242, 1996.

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