Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1993-06-14
1994-06-14
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568426, 568433, C07C 4561, C07C 4500
Patent
active
053211650
ABSTRACT:
A method of producing an ethynyl aromatic aldehyde comprises reacting a protected copper(I) acetylide salt with a halogen substituted aromatic compound to produce a protected ethynyl aromatic aldehyde.
The protected ethynyl aromatic aldehyde may be deprotected to yield an acetylene terminated aromatic aldehyde which is useful for making acetylenic Schiff's base monomers and conductive polymers thereof.
REFERENCES:
patent: 3996290 (1976-12-01), Tavares et al.
patent: 4010207 (1977-03-01), Hall et al.
Austin, W. B. et al., "Facile Synthesis of Ethynylated Benozic Acid Derivves and Aromatic Compounds via Ethynyltrimethylsilane," Journal of Organic Chemistry, vol. 46, No. 11 (1981), pp. 2280-2286.
Dawson, D. J. et al., "Cocyclotrimerization of Aryl Acetylenes: Substituent Effects on Reaction Rate," American Chemistry Society Symposium Series:Polymers for High Technology, vol. 346, ch. 38 (1987), pp. 445-456.
Stephens, R. D. et al., "The Substitution of Aryl Iodides with Cuprous Acetylides, A Synthesis of Tolanes and Heterocyclics," Journal of Organic Chemistry, vol. 28 (Dec. 1963), pp. 3313-3315.
Castro, C. E. et al., "Copper (II) Substitutions, Scope and Mechanism of Cuprous Acetylide Substitutions", Journal of the American Chemical Society, vol. 91 (Nov. 5, 1969), pp. 6464-6470.
Onopchenko, A. et al., "Selective Catalytic Hydrogenation of Aromatic Nitro Groups in the Presence of Acetylenes, Synthesis of (3-Amino-phenyl) acetylene via Hydrogenation of Dimethylcarbinol Substituted (3-Nitrophenyl) acetylene over Heterogeneous Metallic Ruthenium Catalyst," Journal of Organic Chemistry, vol. 44, No. 8 (1979).
Diberardino Thomas
Howell Barbara F.
Lutz Patricia M.
Borda Gary G.
Lone Werren B.
Miller Charles D.
The United States of America as represented by the Secretary of
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