Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing
Patent
1981-04-22
1983-03-15
Meros, Edward J.
Chemistry of inorganic compounds
Silicon or compound thereof
Oxygen containing
252459, 260429R, 260439R, 423326, 423335, 556400, 585733, C01B 3320, C01B 3332
Patent
active
043767575
ABSTRACT:
New crystalline silicate compositions are prepared from a silica containing mixture which is substantially free of aluminum ions and contains a source of choline by digesting a reaction mixture comprising a choline salt, sodium hydroxide, potassium hydroxide, an oxide of silicon, water and, optionally, a Group VIII metal salt with the reaction mixture containing less than about 1000 ppm aluminum. These crystalline silicates exhibit a distinctive X-ray diffraction pattern and have a composition as expressed in terms of its oxides, as follows: ##EQU1## where R is the organic nitrogen-containing cation derived from choline, M is an alkali metal ion, ammonium, hydrogen, a metal cation or mixtures thereof, m is the valence of M, Z is a Group VIII metal cation and z is the valence of said Group VIII metal cation. These crystalline silicates are usefully employed as catalysts in hydrocarbon conversions.
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Hinnenkamp James A.
Walatka, Jr. Vernon V.
Meros Edward J.
National Distillers & Chemical Corp.
Tremain Kenneth D.
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