Synthesis process using photo-induced deligandation

Details Synthesis process using photo-induced deligandation Synthesis process using photo-induced deligandation

1980-06-23

1982-05-18

Williams, Howard S.

Chemistry: electrical and wave energy

Processes and products

Processes of treating materials by wave energy

204158R, 204162R, B01J 1912

Patent

active

043303820

ABSTRACT:
A process is provided for inducing a ligand substitution reaction. The process involves exposing to optical radiation a gaseous mixture including a compound of a transition metal and a first ligand and a gaseous second ligand. The gaseous transition metal compound is preferably a transition metal carbonyl.

REFERENCES:
patent: 3597461 (1971-08-01), L'Eplattenier et al.
patent: 3929601 (1975-12-01), Asprey et al.
patent: 4097384 (1978-06-01), Coleman et al.
Tumas et al., "Olefin Rearrangement Resulting from the Gas Phase KrF. Laser Photolysis of Cr(CO)6", JACS Version, 1/12/81.

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