Synthesis, polymerization and quaternization of N-substituted ac

Details Synthesis, polymerization and quaternization of N-substituted ac Synthesis, polymerization and quaternization of N-substituted ac

1973-05-08

1976-05-04

Schwartz, Gerald A.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260 793R, 260465R, 2604651, 2604659, C07C12300

Patent

active

039548635

ABSTRACT:
N-substituted acrylamidines, a new class of acrylic monomers, are synthesized by the process of this invention which comprises successively contacting with an acrylonitrile or derivative thereof (a) a Lewis acid catalyst, (b) an alkyl halide and (c) an amine. Novel polyacrylamidines as well as quaternary salts of polyacrylamidines are disclosed. Due to their basic nature the N-substituted acrylamidines are useful for introducing basic groups into polymers.

REFERENCES:
patent: 3598800 (1971-08-01), Gatzi
Gordon et al., J. Org. Chem., Vol. 24, pp. 269-271, (1959).
Chemical Abstr., Vol. 70, Column 18, 873(s), (1969).
Chemical Abstr., Vol. 47, Column 3818(g), 3819(c), (1953).

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