Synthesis of vicinal glycols

Details Synthesis of vicinal glycols Synthesis of vicinal glycols

1976-12-09

1978-02-28

Evans, Joseph E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2604488R, 260635R, C07C 2900, C07C 3114

Patent

active

040767582

ABSTRACT:
Relatively low molecular weight primary alcohols are coupled to form relatively higher molecular weight vicinal glycols in which a trialkylsilyl protecting group is employed on the hydroxyl position of said low molecular weight primary alcohol during said coupling reaction.

REFERENCES:
patent: 3076846 (1963-02-01), McClellan
Noll, "Chemistry and Technology of Silicones", (1968), pp. 230, 371.
Sommer, "Stereochemistry, Mechanism and Silocon", Chapter 8, pp. 131-133.
Schwetlick, et al., "Angew. Chem.", vol. 72, (1960), pp. 779-780.
Ladygin, et al., "Kinetics and Catalysis", vol. 6, (1965), pp. 189-195, vol. 7, (1966), pp. 832-839, Translations from the Russian.

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