Synthesis of tetrahydrofuran polymers using calcined silica-alum

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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568617, 264 60, 502 56, 502 81, C07C 4138

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active

052102831

ABSTRACT:
Tetrahydrofuran is polymerized in the presence of a carboxylic acid anhydride and a solid acid catalyst that has been calcined at a temperature greater than about 600.degree. C. Calcined bleaching earth catalysts give THF polymer products having a narrow molecular weight distribution; calcining amorphous silica-aluminas improves their activity toward THF polymerization.

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