Synthesis of sulfilimines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C07C14502

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045785147

ABSTRACT:
Processes are disclosed for preparation of N-aryl-S,S-dihydrocarbylsulfilimines by reaction of phenylisocyanate compounds with hydrocarbyl sulfoxides. The sulfilimines can be rearranged to ortho-thioalkylene anilines and the reactions can be employed in a route for converting nitrobenzene compounds to ortho-thioalkylene anilines, which are useful intermediates for preparation of herbicidal compounds.

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