Synthesis of silyl cyanohydrins

Details Synthesis of silyl cyanohydrins Synthesis of silyl cyanohydrins

1995-08-18

1997-01-14

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

25218313, C07F 710, C07F 718

Patent

active

055941567

ABSTRACT:
A process for preparing silyl cyanohydrins that comprises reacting an aldehyde or ketone with a hydrogen cyanide, a trisubstituted halosilane and a correspondingly substituted disilazane or silyl amine.

REFERENCES:
patent: 3658868 (1972-04-01), Muller et al.
K. Sukata, "A Convenient One-Pot Cyanosilylation of Aldehydes and Ketones Using Potassium or Sodium Cyanide Impregnated on Amberlite XAD Resin and Trimethylsilyl Chloride," vol. 60, No. 10, Bull. Chem. Soc. Jpn. (Oct. 1987), pp. 3820-3822.
"A Facile, One-Pot Synthesis of Silylated Cyanohydrins," Communications, Mar. 1978, pp. 219-222.
"A New Synthesis of .beta.-Aminoalcohols via O-Silylated Cyanohydrins," Communications, Apr. 1981, pp. 270-272.
"A New, One-Pot Synthesis of Silylated Cyanohydrins," Communications, Mar. 1982, pp. 212-214.
"A New Synthesis of 1-Aminoalcohols from O-Trimethylsilylated Cyanohydrins," Communications, Mar. 1986, pp. 301-303.

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