Synthesis of prostaglandins of the "one"-series

Details Synthesis of prostaglandins of the "one"-series Synthesis of prostaglandins of the "one"-series

1975-02-14

1976-11-16

Gerstl, Robert

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260468D, C07C17700

Patent

active

039924394

ABSTRACT:
In the synthesis of prostaglandins of the "one" -series an alteration in the conventional reaction sequence avoids side reactions and provides an improved synthesis via a series of novel intermediates. In this improved synthesis the side chain at the 8 position is attached to the five membered ring before the side chain at the 12 position is attached.

REFERENCES:
patent: 3867460 (1975-02-01), Corey
Doria et al., Tet. Letters, 4307, (1972).
Corey et al., I, JACS, 91, 5675, (1969).
Corey et al., II, JACS, 92, 397, (1970).
Corey et al., III, JACS, 92, 2586, (1970).
Corey et al., IV, JACS, 93, 1490, (1971).

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