Synthesis of poly(dithio thiadiazole by oxidative polymerization

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From sulfur-containing reactant

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526257, 528377, 528493, 528494, 528495, 528496, 528499, C08G 7532

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active

052470610

ABSTRACT:
This invention relates to the preparation of poly(dithio thiadiazole) by combining an oxidizing agent, a dithio thiadiazole, and an aprotic polar solvent thereby producing a polymer precipitant which may then be washed to remove residual contaminants.

REFERENCES:
patent: 4107059 (1978-08-01), King et al.
Minoura et al., "Polymers Containing Thiadiazole Ring", Industrial Chemical Journal, vol. 70, No. 9, pp. 1573-1578 (1967).
E. Weisflog, "On the Synthesis of Alkylthio-, Cycloalkyl Thio- and Cycloalkyl Disulfides by the Oxidation of Mercaptothioethers, Bismercaptothioethers and Bismercaptoalkanes with Iodine and Triethylamine", Phosphorous and Sulfur and Related Elements, vol. 15, No. 1 (1983).
Encyclopedia of Polymer Science and Technology, vol. II, "Polysulfide Polymers", pp. 425-447 (1969).
Organic Chemistry, Ch. 6, "Role of the Solvent", pp. 223-247 (1987).
Standard Aqueous Electrode Potentials and Temperature Coefficients at 25.degree. C. by de Bethune and Loud (1966).

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