Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate
Reexamination Certificate
2005-06-29
2009-08-25
Eashoo, Mark (Department: 1796)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From phenol, phenol ether, or inorganic phenolate
C528S086000
Reexamination Certificate
active
07579427
ABSTRACT:
A new series of wholly aromatic poly(arylene ether ether ketone ketone)s containing pendant sulfonic acid groups (SPAEEKK) were conveniently prepared by potassium carbonate mediated nucleophilic polycondensation reactions of inexpensive commercially available monomers: 1,3-bis(4-fluorobenzoyl)benzene (BFBB), sodium 6,7-dihydroxy-2-naphthalenesulfonate (DHNS), and 4,4′-biphenol or hydroquinone in N-methyl-2-pyrrolidone (NMP) at 170° C. FT-IR and NMR were used to characterize the structures and the sulfonate or sulfonic acid contents (SC) of the polymers. Flexible membrane films were obtained by casting N,N-dimethylacetamide (DMAc) solutions of copolymers. Membrane films in acid form were then obtained by treating the sodium form membrane films in 2 N sulfuric acid at room temperature. Glass transition temperatures (Tgs) and decomposition temperatures (Tds) of SPAEEKKs in both sodium and acid forms were determined. Water uptake and swelling ratio values increased with SCs and temperatures. The proton conductivities of acid form membrane films increased with SC value and temperature and reached 5.6×10−2S/cm at 100° C. for SPAEEKK-100.
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Naphthalene, Hawley's Condensed Chemical Dictionary, John Wiley and Sons, Inc, 14th Edition http://www.knovel.com/knovel2/HTML—Viewer—Main.jsp?BookID=704&SetID=5311004&TextID=0&Type=null&CurrentPage=0&1sSearch=true&FromSearch=true.
Gao Yan
Guiver Michael D.
Robertson Gilles P.
Anderson J. Wayne
Eashoo Mark
Heincer Liam J
National Research Council of Canada
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