Synthesis of phosphono-substituted porphyrin compounds for...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C548S400000

Reexamination Certificate

active

08080653

ABSTRACT:
A method of making a phosphono-substituted dipyrromethane comprises reacting an aldehyde or acetal having at least one phosphono group substituted thereon with pyrrole to produce a phosphono-substituted dipyrromethane; and wherein the phosphono is selected from the group consisting of dialkyl phosphono, diaryl phosphono, and dialkylaryl phosphono. Additional methods, intermediates and products are also described.

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Muthukumaran, et al., J.O.C., 2004, 69(5), 1444-1452.
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Lindsey et al., “Investigation of the Synthesis of Ortho-Substituted Tetraphenylphorphyrins,” Apr. 21, 1988, J. Org. Chem., vol. 54, pp. 828,836, especially p. 833.
Kim et al., “Curing of Epoxides with O,O-Di-t-butyl Phenylphosphonate as Thermally Latent Initiator,” Sep. 29, 2000, J. Applied Polymer Science, vol. 81, pp. 2347-2351, especially p. 2349.
Rao et al., J. Org. Chem., vol. 65, No. 22, 2000, pp. 7323-7344.
Gryko et al.; “Parallel synthesis ofmeso-substituted corroles andmeso-substituted [22]pentaphyrins(1.1.1.0.0) from diacyldipyrromethanes”J. Porphyrins Phthalocyanines7 239-248 (2003).
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