Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-01-02
1976-11-16
Myers, Jane S.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260465D, 2604654, 260485J, 260485L, 260485P, C07C 6936
Patent
active
039924360
ABSTRACT:
A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of carboxylic ortho esters with carbon monoxide and oxygen-containing gas in the presence of a metal salt catalyst, an amine base and a catalytic amount of an alcohol. Preferably a catalytic amount of particular metal oxidizing salts is employed along with a catalytic amount of an acid or an amine salt compound. Alternatively various counterions and ligands of the metal salt catalysts may be employed.
REFERENCES:
patent: 3393136 (1968-07-01), Fenton et al.
Atlantic Richfield Company
McCaslin Delbert E.
Myers Jane S.
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