Synthesis of oxalate esters by the oxidative carbonylation of al

Details Synthesis of oxalate esters by the oxidative carbonylation of al Synthesis of oxalate esters by the oxidative carbonylation of al

1982-08-06

1984-05-29

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560190, 502170, 502172, 502209, C07C 6736

Patent

active

044516665

ABSTRACT:
Synthesis of dialkyl oxalates by the heterogeneous catalyzed oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with a crystalline vanadium-phosphorus-manganese containing compound.

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patent: 4281174 (1981-07-01), Current
Fenton et al. II, J. Organ. Chem., vol. 39, No. 5, (1974), pp. 701-704.

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