Synthesis of olefinic oxides from olefin and oxygen

Details Synthesis of olefinic oxides from olefin and oxygen Synthesis of olefinic oxides from olefin and oxygen

1978-07-10

1981-03-17

Milestone, Norma S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D30106

Patent

active

042566495

ABSTRACT:
Propylene oxide and other olefinic oxides are synthesized by reacting an olefin and oxygen in the presence of a catalytic amount of a complex. The complex is of the type L.sub.2 MX.sub.2, L.sub.2 M or L.sub.2 MR where M is palladium, X is an acidic anion (preferably chloride); R is an olefinic group (preferably a propylene group) and L.sub.2 consists of two monodentate ligands or a single bidentate ligand.

REFERENCES:
patent: 2776301 (1957-01-01), Payne et al.
patent: 3993673 (1976-11-01), McMullen
A. Fusi et al., Jour. of Organometallic Chem., vol. 26 (1971), pp. 426-427.
James E. Lyons et al., Tetrahedron Letters No. 29 (1972), pp. 12903-12906.
Lyons, J. E., Advances in Chemistry Series, Homogeneous Catalysis-II, pp. 64-68, 73.
Lyons, J. E., et al., J. Org. Chem., vol. 37, No. 18 (1972), pp. 2881-2884.

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