Synthesis of novel molecular sieves using a metal complex as a t

Details Synthesis of novel molecular sieves using a metal complex as a t Synthesis of novel molecular sieves using a metal complex as a t

1994-08-24

1996-02-06

Bell, Mark L.

Chemistry of inorganic compounds

Zeolite

Organic compound used to form zeolite

423703, 423718, 423DIG30, 502 62, 502214, C01B 3708, C01B 3904

Patent

active

054894247

ABSTRACT:
The synthesis and characterization of novel molecular sieves containing bis(pentamethylcyclopentadienyl) cobalt(III) ion are described. Several types of molecular sieves were prepared using the cobalt metal complex as a template that was shown to be incorporated as a guest molecule within the molecular sieve. Molecular sieves prepared using bis(pentamethylcyclopentadienyl) cobalt(III) ion as template were characterized as having a pore size at least as large as 7 .ANG.. Other molecular sieves were also prepared using bis(cyclopentadienyl) cobalt(III) templates. The compounds are attractive as catalysts in a wide range of applications.

REFERENCES:
patent: 4100262 (1978-07-01), Pelrine
patent: 4440871 (1984-04-01), Lok et al.
patent: 4556549 (1985-12-01), Valyocsik
patent: 4568654 (1986-02-01), Valyocsik
patent: 4744970 (1988-05-01), Lok et al.
patent: 5106801 (1992-04-01), Zones et al.
patent: 5167942 (1992-12-01), Balkus et al.
patent: 5316753 (1994-05-01), Nakagawa
patent: 5334367 (1994-08-01), Rosinski et al.
Balkus and Gabrielov, "The Synthesis and Characterization of UTD-1. A Novel Molecular Sieve containing bis(pentamethylcyclopentadienyl) cobalt(III) Ion," ACS, Anaheim, Calif., Apr. 1995.
Balkus and Shepelev, "Synthesis of nonasil molecular sieves in the presence of cobalticinium hydroxide," Microporous Materials, 1:383-391, 1993 (No month).
Balkus et al. "Synthesis of Aluminum Phosphate Molecular Sieves using Cobalticinium Hydroxide," Microporous Materials, vol. 3 No. 4-5 Jan. 1995 pp. 489-495.
Balkus et al., "Synthesis of NaX Zeolites with Metallophthalocyanines," Supramolecular Architecture, ACS Symposium Series 499:347-354, 1992. (No month).
Bekkum et al., "Introduction To Zeolite Science and Practice," Studies in Surface Science and Catalysis, 58:137-151, 1991. (No month).
Kolle and Khouzami, "Decamethylcobaltocen: Synthese and Umwandlung in methylierte (Aren) (cyclopentadienyl)cobalt-Kationen," Chemische Berichte, 114:2929-2937, 1981. (No month).
Szostak, "Principles of Synthesis and Identification," Molecular Sieves, 92-101, 1989. (No month).
van de Goor et al "The Cobalticinium Cation [Co.sub.14 (N.sup.5 -C.sub.5 H.sub.5).sub.2 ].sup.+ : A Metal-Organic Complex as a Novel Template for the Synthes of Clathrasils" Z. Anory. Aug. Chem. 621, 311-322 1995.
Ozin et al. "Intrazeolite Metallocene: Chemistry, Spectroscopy, and Dynamics" J. Phys. Chem vol. 93 (1989) pp. 878-893.
Dutta et al "Resonance Raman Spectroscopic Studies of Cobalticinium Ion in Zeolite Y: Influence of Cations & Hydration" Zeolites vol. 6 No. 6 1986 pp. 423-426.

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