Synthesis of novel molecular sieves using a metal complex as a t

Details Synthesis of novel molecular sieves using a metal complex as a t Synthesis of novel molecular sieves using a metal complex as a t

1995-05-11

1997-02-18

Bell, Mark L.

Chemistry of inorganic compounds

Zeolite

Organic compound used to form zeolite

423703, 423705, 423DIG30, C01B 3708

Patent

active

056039140

ABSTRACT:
The synthesis and characterization of novel molecular sieves containing bis(pentamethylcyclopentadienyl) cobalt(III) ion are described. Several types of molecular sieves were prepared using the cobalt metal complex as a template that was shown to be incorporated as a guest molecule within the molecular sieve. Molecular sieves prepared using bis(pentamethylcyclopentadienyl) cobalt(III) ion as template were characterized as having a pore size at least as large as 7 .ANG.. Other molecular sieves were also prepared using bis(cyclopentadienyl) cobalt(III) templates. The compounds are attractive as catalysts in a wide range of applications.

REFERENCES:
patent: 4440871 (1984-04-01), Lok et al.
patent: 4556549 (1985-12-01), Valyocsik
patent: 4568654 (1986-02-01), Valyocsik
patent: 4744970 (1988-05-01), Lok et al.
patent: 5167942 (1992-12-01), Balkus et al.
patent: 5316753 (1994-05-01), Nakagawa et al.
Lok et al. "The Role of Organic Molecules in Molecular Sieve Synthesis" Zeolites vol. 3 Oct. 1983 282-91.
Balkus et al. "The Synthesis & Characterization of UTD-1 . . . " ACS Apr. 1995.
Balkus et al. "Synthesis of Nonasil Molecular Sieves in the Presence of Cobalticinium Hydroxide" Microporous Materials vol. 1 pp. 383-391 (1993).
Balkus et al. "Synthesis of Aluminum Phosphate Molecular Sieves using Cobalticinium Hydroxide" Microporous Mat'ls vol. 3 Nos. 4-5 Jan. 1995 pp. 489-495.
Balkus et al "Synthesis of NaX Zeolites with Metallophthalocyanines" Supramolecular Architecture ACS Symposium Series 499 pp. 347-354 1992.
Wilson "Synthesis of AlPO.sub.4 Based Molecular Sieves" Introduction to Zeolite Science & Practice (Eds. Bekkum et al.) vol. 58 pp. 137-151 1991.
K olle et al. "Decamethyl Cobaltecen: Synthese und Umwaoluny in Methylierte (Aren) (Cyclopentadienyl) Cobalt Kationen" Chemishe Berichte vol. 114 pp. 2929-2937 1981.
Szostak Molecular Sieves: Principles of Synthesis & Identification pp. 92-101 1989.
Behrens et al. "Metal-Organic Complexes as New Templates for Synthesis of Clathrasils" 8th Int'l Symp. on Molecular Recognition & Inclusion Jul.-Aug. 1994 p. 58.
Van der Goor "The Cobalticinium Cation [Co.sup.III(n.sup.5 -C.sub.2 H.sub.5).sub.2 ]: A Metal Complex as a Novel Template for the Synthesis of Clathrasils" Z. Anorg. Chem 621(1995) 311-325.

Affiliated with

Also associated with

Rating

Synthesis of novel molecular sieves using a metal complex as a t does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Synthesis of novel molecular sieves using a metal complex as a t, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Synthesis of novel molecular sieves using a metal complex as a t will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1600697