Chemistry of inorganic compounds – Zeolite – Organic compound used to form zeolite
Patent
1995-05-11
1997-07-15
Bell, Mark L.
Chemistry of inorganic compounds
Zeolite
Organic compound used to form zeolite
423703, 423718, 423DIG30, 502 64, 502214, C01B 3702, C01B 3708
Patent
active
056480580
ABSTRACT:
The synthesis and characterization of novel molecular sieves containing bis(pentamethylcyclopentadienyl) cobalt(III) ion are described. Several types of molecular sieves were prepared using the cobalt metal complex as a template that was shown to be incorporated as a guest molecule within the molecular sieve. Molecular sieves prepared using bis(pentamethylcyclopentadienyl) cobalt(III) ion as template were characterized as having a pore size at least as large as 7 .ANG.. Other molecular sieves were also prepared using bis(cyclopentadienyl) cobalt(III) templates. The compounds are attractive as catalysts in a wide range of applications.
REFERENCES:
patent: 4100262 (1978-07-01), Pelrine
patent: 4310440 (1982-01-01), Wilson et al.
patent: 4440871 (1984-04-01), Lok et al.
patent: 4556549 (1985-12-01), Valyocsik
patent: 4568654 (1986-02-01), Valyocsik
patent: 4744970 (1988-05-01), Lok et al.
patent: 5091073 (1992-02-01), Chang et al.
patent: 5094828 (1992-03-01), Chu et al.
patent: 5106801 (1992-04-01), Zones et al.
patent: 5167942 (1992-12-01), Balkus et al.
patent: 5316753 (1994-05-01), Nakagawa
patent: 5334367 (1994-08-01), Rosinski et al.
Balkus et al. "The Synthesis & Characterization of UtD-1 . . . " ACS Anaheim California, Apr. 1995.
Balkus et al. "Synthesis of Nonasil Molecular Sieves in the Presence of Cobalticinium Hydroxide" Microporous Matls. 1 pp. 583-591 1993.
Balkus et al. "Synthesis of Aluminum Phosphate Molecular Sieves Using Cobalticinium Hydroxide" Microporous Material vol. 3 No. 4-5, Jan. 1995 p. 489.
Balkus et al. "Synthesis of NaX Zeolites With Metallophthalocyannes" Supramolecular Achitecture, ACS Symposium Series vol. 499, p. 347 1992.
Bekkum et al. "Introduction to Zeolite Science & Practice" Studies in Surface Science & Catalysis vol 58 p. 137 1991.
Kolle et al. "Decylmethylcobaltelen: Synthese und Umwandlung In Methylierte (Aren) (Cyclopentadienyl) Cobalt -Kationrn" Chemische Berichde vol. 114 p. 2926 1981.
Szostak "Molecular Sieves: Principles of Synthesis & Identification" pp. 92-101 1989.
Behrens et al. "Metal Organic Complexes As Templates For The Synthesis of Clathrasils" 8th IntL Symp. on Mol Recounition & Inclusion p. 53.
Van der Gour et al. "The cobalticinium cation: A Metal -Organic Complex As A Novel Template For The Sinth of Clatyrasics" Z. Anory. Ally. Chem. vol 621 pp. 311-322 1995.
Meier & Olson Altas of Zeolite Structures pp. 22, 23 26, 27, 96, 97, 114, 115 & 180-181 1992.
Balkus, Jr. Kenneth J.
Gabrielov Alexi G.
Bell Mark L.
Board of Regents, The Univ. of Texas System
Sample David
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