Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-05-10
1977-10-25
Sneed, Helen M. S.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
252431P, 260666B, 26068315D, C07F 1504, C07F 1500
Patent
active
040555828
ABSTRACT:
A process is disclosed comprising reacting at least one compound of the formula RMX(PR.sub.3).sub.2 and at least one compound of the formula APR.sub.2 to produce at least one composition which can be represented by the formula M(PQ.sub.3).sub.n, wherein M is palladium or nickel; X is a halogen; A is an alkali metal; each R is individually selected from the group consisting of suitable aliphatic hydrocarbyl radicals, halosubstituted aliphatic hydrocarbyl radicals, aromatic hydrocarbyl radicals wherein at least one carbon adjacent the radical carbon has a hydrogen substituent, halosubstituted aromatic hydrocarbyl radicals wherein at least one carbon adjacent the radical carbon has a hydrogen substituent, hydrocarbyloxy radicals, and halosubstituted hydrocarbyloxy radicals, each Q is individually selected from any R contained in the reactants; each PR.sub.3 may be the same or different; each PQ.sub.3 may be the same or different; the molar ratio of each different PQ.sub.3 to M can be any rational number such that the sum of the molar ratios of the different PQ.sub.3 's equals n; and n equals 3 when M is palladium or 4 when M is nickel.
REFERENCES:
patent: 3102899 (1963-09-01), Cannell
patent: 3519663 (1970-07-01), O'Brien et al.
patent: 3671560 (1972-06-01), Fahey
patent: 3776929 (1973-12-01), Mrowca
patent: 3799961 (1974-03-01), Varshavsky
patent: 3808246 (1974-04-01), Fahey
patent: 3818063 (1974-06-01), Fahey
patent: 3891684 (1975-06-01), Jung
Cundy, J. Organometal. Chem. 69, pp. 305-310 (1974).
Issleib et al., Ber. 95, pp. 2742-2746 (1962).
Tolman, J.A.C.S. 92 (10), pp. 2956-2965 (1970).
Parshall, J.A.C.S. 96 (8), pp. 2360-2365 (1974).
Chatt et al., J. Chem. Soc. Part II, pp. 1718-1729 (1960).
Issleib, L. Fur Chem. "Zur Reaklivitat P-substituierter Alkali phosphide" v.2, pp. 168-169 (1962).
Phillips Petroleum Company
Sneed Helen M. S.
LandOfFree
Synthesis of nickel and palladium organophosphorus complexes does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Synthesis of nickel and palladium organophosphorus complexes, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Synthesis of nickel and palladium organophosphorus complexes will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-122764