Synthesis of NaBH.sub.3 CN and related compounds

Chemistry of inorganic compounds – Boron or compound thereof – Nitrogen and hydrogen containing

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568 1, C01B 615, C07F 502

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active

043011292

ABSTRACT:
A process for the preparation of compounds of the formula RBH.sub.3 CN wherein R is an alkali metal, a quaternary ammonium radical or a phosphonium radical wherein a compound of the formula RCN is treated with a stoichiometric amount or slightly less than a stoichiometric amount of a BH.sub.3 donor is described. The final products are useful as hydrolysis stable reductants and as synthetic intermediates.

REFERENCES:
patent: 3634277 (1972-01-01), Brown
patent: 3667923 (1972-06-01), Wade et al.
patent: 3697232 (1972-10-01), Wade et al.
Wade et al.; "Inorg. Chem.", 9 1970, pp. 2146-2150.

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