Synthesis of metal nanoparticle compositions from metallic...

Specialized metallurgical processes – compositions for use therei – Processes – Producing or purifying free metal powder or producing or...

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C075S369000

Reexamination Certificate

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10875806

ABSTRACT:
A process of making metal nanoparticles comprising the steps of: providing a precursor composition comprising at least one metallic compound and at least one organic compound; wherein the organic compound is selected from the group consisting of an ethynyl compound, a metal-ethynyl complex, and combinations thereof; wherein the precursor composition is a liquid or a solid at room temperature; and heating the precursor composition under conditions effective to produce metal nanoparticles. A metal nanoparticle composition comprising metal nanoparticles dispersed homogenously in a matrix selected from the group consisting of ethynyl polymer, crosslinked ethynyl polymer, amorphous carbon, carbon nanotubes, carbon nanoparticles, graphite, and combinations thereof.

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Weyland, Tania et al., “[(Cp*)(dppe)Fe(III)-]+ Units Bridged through 1,3-Diethynylbenzene and 1,3,5-Triethynylbenzene Spacers: Ferromagnetic Metal—Metal Exchange Interaction”,Organometallics,vol. 17, 1998, pp. 5569-5579.
Hutton, Howard et al., “Preparation of Nanoscale Platinum(0) Clusters in Glassy Carbon andTheir Catalytic Activity”,Chem. Mater., vol. 5, 1993, pp. 1727-1738.

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