Synthesis of lower alkyl amines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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252466J, C07C 8502

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active

043140840

ABSTRACT:
This invention relates to an improved process for synthesizing lower alkyl amines via the gas phase ammonolysis of a lower alkanol. The improvement in the gas phase ammonolysis process resides in the use of a finely divided hydrogenation catalyst comprising a group 8 metal supported on a comparatively neutral alumina substrate, said neutrality to the support being imparted by the addition of an alkaline earth metal.

REFERENCES:
patent: 2033866 (1936-03-01), Schranth
patent: 2636902 (1953-04-01), Taylor
patent: 2795600 (1957-06-01), Chitwood
patent: 3274253 (1966-09-01), Markiewitz
patent: 4014933 (1977-02-01), Boettger et al.
patent: 4036883 (1977-07-01), Voges et al.

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