Synthesis of hydrosilanes from methylchloropolysilanes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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423324, 423342, 423347, C07F 708, C07F 712, C01B 3308, C01B 3304

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active

040790711

ABSTRACT:
The present invention relates to a process for preparing high yields of hydrosilanes by reacting methylchloropolysilanes with hydrogen gas under pressure at a temperature of from about 25.degree. C to about 350.degree. C in the presence of a copper catalyst. Useful copper catalysts include copper metal, copper salts, and complexes of copper salts with organic ligands.

REFERENCES:
patent: 2787627 (1957-04-01), Kuriyagawa et al.
patent: 3432537 (1969-03-01), Guinet et al.
patent: 3639105 (1972-02-01), Atwell et al.
patent: 3878234 (1975-04-01), Atwell et al.

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