Synthesis of heteronuclear tri-osmium carbonyl hydrides under ga

Details Synthesis of heteronuclear tri-osmium carbonyl hydrides under ga Synthesis of heteronuclear tri-osmium carbonyl hydrides under ga

1981-11-18

1983-06-21

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260439CY, 423417, C07F 1100, C07F 1502, C07F 1504, C07F 1506

Patent

active

043893473

ABSTRACT:
A process for producing a tri-osmium heteronuclear metal carbonyl compound comprises establishing a reaction mixture comprising an electron deficient cobalt, nickel, iron, molybdenum or rhodium carbonyl, H.sub.2 Os.sub.3 (CO).sub.10 and a solvent in the presence of gaseous hydrogen and recovering the tri-osmium heteronuclear metal carbonyl compound from the reaction mixture. Some of the cobalt, molybdenum and rhodium carbonyls produced are new.

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Churchhill et al., J. Chem. Comm., p. 534, (1978).

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