Synthesis of gem-dinitroalkanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568932, C07C 4327, C07C 7910

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active

042208041

ABSTRACT:
Substituted gem-dinitroalkanes are prepared by reacting a nitro olefin, tetranitromethane and an alcohol or organolithium derivative. The substituted gem-dinitroalkanes are useful as explosives, plasticizers and binders.

REFERENCES:
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patent: 2991315 (1961-07-01), Plummer
patent: 3049570 (1962-08-01), Plummer
patent: 3316311 (1967-04-01), Plummer
patent: 3629345 (1971-12-01), Harpell
Novikov et al., Izvestiya Akademii Nauksssr, Otdelenie Khim. Nauk, No. 7, . 1295 to 1296 (1960).
Langercrantz et al., Acta. Chem. Scand., vol. 24, pp. 550 to 560 (1970).

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