Synthesis of esters from alcohols containing carbon monoxide as

Details Synthesis of esters from alcohols containing carbon monoxide as Synthesis of esters from alcohols containing carbon monoxide as

1985-10-02

1990-07-03

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560232, 568485, 568487, 568902, C07C 6740, C07C 6906, C07C 6914, C07C 6924

Patent

active

049392921

ABSTRACT:
Esters are prepared by contacting, under suitable reaction conditions, a feed stream comprising a primary alcohol of 1-4 carbon atoms per molecule (preferably methanol, ethanol) and carbon monoxide with a catalyst composition comprising (a) copper or a copper compound (preferably CuO), (b) zinc oxide, (c) at least one metal or compound of at least one metal selected from the group consisting of cobalt, ruthenium, iridium, platinum, molybdenum, and rhenium (preferably cobalt and/or rhenium) and, optionally, (d) alumina.

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